Introduction to Crystal Chemistry: Student EditionCUP Archive, 1988年9月30日 - 161 頁 First published in 1988 this textbook on crystal chemistry covers the basic principles of crystal chemistry and physics and crystallography and introduces the concept of crystal refractivity. The book begins with a discussion of atoms and atomic structure and moves from there to atomic bonding. Throughout this discussion, special emphasis is given to Pauling's rules. The author then treats crystal symmetry, crystal field theory, polyhedral structure and atomic packing. He concludes by introducing the student to more sophisticated optical properties of minerals, refractivity and polarisability in crystals. The material covered is sufficiently basic so that the book will be suitable for undergraduate and graduate student in advanced mineralogy courses. It will also be of interest to individuals, including mineralogists, materials scientists, crystallographers and inorganic chemists who are engaged in academic and industrial research dealing with the structure of the solid state. |
內容
spectra and quanta ionization | 15 |
The crystal chemistry of the covalent bond | 27 |
The crystal chemistry of the ionic bond | 42 |
Paulings second rule of electrostatic valency in ionic | 61 |
External nontranslational and internal translational | 71 |
Crystal field theory | 89 |
Polyhedral distortion | 95 |
Density volume unit cells and packing | 117 |
selected representative crystal structures | 147 |
153 | |
常見字詞
ų anions array atomic number axes axis biaxial bond type cation chemical bond close packing cm³ compounds coordination numbers corners covalent bond crystal chemistry crystal field theory crystal structure crystal systems cube cubic diadochy diamond distorted electric charge electron density electronegativity electronegativity differences electronic structure elements equal Fe2+ Figure formula g/cm³ garnet H₂O halite hexagonal hybrid bond orbital index of refraction interatomic distance ionic bonding ionic radii Ionic-covalent ionization potential ions isometric isostructural Jaffe lobes Mg Mg minerals Mn2+ molecular neutrons nucleus nuclides octahedral octahedral sites octahedron olivine optical overlap oxide oxygen anions pairs Pauling Pauling's planes polarizability polyhedra pyrite quantum number radioactive radius ratio rare gas Si4+ silicate solid solution sp³ hybrid space group specific refractivity spectral spin spinel symmetry synthetic Table tennis balls tetragonal tetrahedral transition metal unit cell valence electrons values velocity VIII wavelength X-ray zircon