Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
內容
| 1 | |
| 13 | |
| 23 | |
| 33 | |
Vanadium Haloperoxidases | 55 |
Molybdenum and Tungsten Enzymes | 81 |
Catalysis by Nitrogenases and Synthetic Analogs | 153 |
Biological IronSulfur Clusters with Catalytic Activity | 209 |
Dioxygen Activation at Heme Centers in Enzymes and Synthetic Analogs | 323 |
Biological and Biomimetic Catalysis of Manganese Redox Enzymes and Their Inorganic Models | 355 |
The Two B12 Cofactors Influence of the trans Nitrogen Ligand on Homolytic and Heterolytic Processes | 423 |
Formation Structure and Reactivity of Copper Dioxygen Complexes | 469 |
Multielectron Transfer and Catalytic Mechanisms in Oxidative Polymerization | 535 |
Metalloenzymes with a Quinone Cofactor | 563 |
Future Developments | 587 |
Index | 595 |
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases dmso donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen atom peroxo phenol polymerization porphyrin proposed protein radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase