Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 1 到 5 筆結果,共 79 筆
第 10 頁
... tion and consumption of dioxygen , dinitrogen fixation , conversion of solar en- ergy , communication between cells with electric signals , and ways to apply this knowledge ? Before application is possible , understanding is necessary ...
... tion and consumption of dioxygen , dinitrogen fixation , conversion of solar en- ergy , communication between cells with electric signals , and ways to apply this knowledge ? Before application is possible , understanding is necessary ...
第 18 頁
... tion ( Eq . 7 ) can proceed via two - step homolytic mechanisms . ArCH3 + Mn + → ArCH2 + Mn - 1 ) + + H + RX + M → [ R ' + MX ] → R - M - X M + O2 MOO → M — 0—0- ( 5 ) ( 6 ) ( 7 ) Furthermore , it should be noted that the same metal ...
... tion ( Eq . 7 ) can proceed via two - step homolytic mechanisms . ArCH3 + Mn + → ArCH2 + Mn - 1 ) + + H + RX + M → [ R ' + MX ] → R - M - X M + O2 MOO → M — 0—0- ( 5 ) ( 6 ) ( 7 ) Furthermore , it should be noted that the same metal ...
第 24 頁
... tion of the support . However , it is now clear that the support's role is anything but passive in many reactions . For example , the acidity or basicity of the support material can have a crucial effect on the overall reaction to be ...
... tion of the support . However , it is now clear that the support's role is anything but passive in many reactions . For example , the acidity or basicity of the support material can have a crucial effect on the overall reaction to be ...
第 25 頁
... tion than is the zeolite . IV . KINETICS OF REACTION The kinetics of enzyme reactions was first established by Michaelis and Menten , following the earlier work of Henri [ 23 ] . The famous Michaelis - Menten equation for the kinetics ...
... tion than is the zeolite . IV . KINETICS OF REACTION The kinetics of enzyme reactions was first established by Michaelis and Menten , following the earlier work of Henri [ 23 ] . The famous Michaelis - Menten equation for the kinetics ...
第 26 頁
... tion . Clearly , k is equivalent to the enzymological Vmax ; PA - the reactant pressure in a gas phase reaction - is equivalent to [ S ] ; and 1 / K is equivalent to Km . The identity in kinetic expression between enzymatic and ...
... tion . Clearly , k is equivalent to the enzymological Vmax ; PA - the reactant pressure in a gas phase reaction - is equivalent to [ S ] ; and 1 / K is equivalent to Km . The identity in kinetic expression between enzymatic and ...
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
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第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
第 534 頁 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
第 316 頁 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
第 202 頁 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
第 204 頁 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
第 30 頁 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
第 30 頁 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
第 528 頁 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).