Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 1 到 5 筆結果,共 79 筆
第 7 頁
... species . Substrates and reagents in catalytic reactions can vary from simple species like O2 , H2O , NH3 , H2 , N2 , CO2 , and NO2 to larger molecules such as ethanol , alkenes , and phenols . Many of these substrate molecules will be ...
... species . Substrates and reagents in catalytic reactions can vary from simple species like O2 , H2O , NH3 , H2 , N2 , CO2 , and NO2 to larger molecules such as ethanol , alkenes , and phenols . Many of these substrate molecules will be ...
第 37 頁
... species distribution at various pH's were totally unknown . ( 3 ) Possible catalytically active species L- Mn + OH were not identified by means of the thermodynamic pK1 values . Those described were all obtained merely in kinetics . ( 4 ) ...
... species distribution at various pH's were totally unknown . ( 3 ) Possible catalytically active species L- Mn + OH were not identified by means of the thermodynamic pK1 values . Those described were all obtained merely in kinetics . ( 4 ) ...
第 38 頁
... species 3b ( generated with pK < 6 ) was postulated to be an active catalytic species . In this study , the stability constants for 3 and 9 and the thermodynamic pK , value of the Cu2 + -bound water for 3a → 3b + H + were not measured ...
... species 3b ( generated with pK < 6 ) was postulated to be an active catalytic species . In this study , the stability constants for 3 and 9 and the thermodynamic pK , value of the Cu2 + -bound water for 3a → 3b + H + were not measured ...
第 39 頁
... species proba- bly is a ZnL - OH- complex ( 5b ) with pK , values of 8.7 ( R = CH3 ) and 9.1 ( R = C17H35 ) for 5a5b + H + . The DNP hydrolysis kinetics in comicellar solution of 20 mM Brij 35 and 0.25 mM ZnL Br ( ClO4 ) ( R = C17H35 ) ...
... species proba- bly is a ZnL - OH- complex ( 5b ) with pK , values of 8.7 ( R = CH3 ) and 9.1 ( R = C17H35 ) for 5a5b + H + . The DNP hydrolysis kinetics in comicellar solution of 20 mM Brij 35 and 0.25 mM ZnL Br ( ClO4 ) ( R = C17H35 ) ...
第 46 頁
... species 3b obtained in the equilib- rium studies . This means that among 11a , 11b , and 13 , the kinetically reactive species is only the monomeric hydroxide - bound zinc ( II ) complex 11b , as defined by the kinetic equation 6. The ...
... species 3b obtained in the equilib- rium studies . This means that among 11a , 11b , and 13 , the kinetically reactive species is only the monomeric hydroxide - bound zinc ( II ) complex 11b , as defined by the kinetic equation 6. The ...
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
熱門章節
第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
第 534 頁 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
第 316 頁 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
第 202 頁 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
第 204 頁 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
第 30 頁 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
第 30 頁 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
第 528 頁 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).