Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 34 頁
... reported on optimization of the ligands and metal ions . The most general problem encountered in the past was that chelating ligands , which leave the catalytic sites vacant , tend to dissociate from the metals at neutral pH in aqueous ...
... reported on optimization of the ligands and metal ions . The most general problem encountered in the past was that chelating ligands , which leave the catalytic sites vacant , tend to dissociate from the metals at neutral pH in aqueous ...
第 35 頁
... reported with a specific aim of developing decontaminants . The exploration of good metal catalysts for lipophilic phosphates may also be useful for hydrolysis of phospholipids , which is relatively unexplored . II . ORGANOPHOSPHORUS ...
... reported with a specific aim of developing decontaminants . The exploration of good metal catalysts for lipophilic phosphates may also be useful for hydrolysis of phospholipids , which is relatively unexplored . II . ORGANOPHOSPHORUS ...
第 40 頁
... reported another type of metal- lomicelle attached with a metal - bound alkoxide nucleophile . Tagaki's zinc ( II ) and copper ( II ) complexes ( with possible structures 6a and b ) promoted the hydro- lysis of 4 - nitrophenyl ...
... reported another type of metal- lomicelle attached with a metal - bound alkoxide nucleophile . Tagaki's zinc ( II ) and copper ( II ) complexes ( with possible structures 6a and b ) promoted the hydro- lysis of 4 - nitrophenyl ...
第 41 頁
... reported comicellar system with 3b . The active species was proposed to be the hydroxide - bound copper ( II ) complex 8b . The pK , value of the copper ( II ) -bound water molecule was speculated to be about 8 from the fact that the ...
... reported comicellar system with 3b . The active species was proposed to be the hydroxide - bound copper ( II ) complex 8b . The pK , value of the copper ( II ) -bound water molecule was speculated to be about 8 from the fact that the ...
第 49 頁
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acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
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第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
第 534 頁 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
第 316 頁 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
第 202 頁 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
第 204 頁 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
第 30 頁 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
第 30 頁 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
第 528 頁 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).