Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 1 到 5 筆結果,共 87 筆
第 36 頁
... Proposed mechanism for paraoxon hydrolysis by organophosphorus hydrolase ( X and X ' are unspecified ligands ) . value from 3170 sec1 in the wild - type enzyme to less than 10 sec 1 , whereas substitution for the other histidines ...
... Proposed mechanism for paraoxon hydrolysis by organophosphorus hydrolase ( X and X ' are unspecified ligands ) . value from 3170 sec1 in the wild - type enzyme to less than 10 sec 1 , whereas substitution for the other histidines ...
第 38 頁
... proposed to exist in the hydroxamate form , there were no experimental data for the stability and structure of metal complexes at pH 11.5 ( e.g. , it is not known whether the -NO2 O = P - 0 HO OH2 Cu2 + Diphenyl 4 - Nitrophenyl ...
... proposed to exist in the hydroxamate form , there were no experimental data for the stability and structure of metal complexes at pH 11.5 ( e.g. , it is not known whether the -NO2 O = P - 0 HO OH2 Cu2 + Diphenyl 4 - Nitrophenyl ...
第 39 頁
... Proposed mechanism for acetyl phosphate hydrolysis by Gutsche's metallomi- celle 4 : ( a ) acetyl transfer mechanism , ( b ) general base mechanism . N- N N H NO2 Figure 3 Proposed difunctional or Lewis Acid Properties of Zinc 39.
... Proposed mechanism for acetyl phosphate hydrolysis by Gutsche's metallomi- celle 4 : ( a ) acetyl transfer mechanism , ( b ) general base mechanism . N- N N H NO2 Figure 3 Proposed difunctional or Lewis Acid Properties of Zinc 39.
第 40 頁
Jan Reedijk, Elisabeth Bouwman. N- N N H NO2 Figure 3 Proposed difunctional or " push - pull " mechanism for diphenyl 4 - nitrophenyl phosphate by Breslow's metallomicelle 5 . proposed for 5b ( see Figure 3 ) , in which zinc ( II ) ...
Jan Reedijk, Elisabeth Bouwman. N- N N H NO2 Figure 3 Proposed difunctional or " push - pull " mechanism for diphenyl 4 - nitrophenyl phosphate by Breslow's metallomicelle 5 . proposed for 5b ( see Figure 3 ) , in which zinc ( II ) ...
第 41 頁
... proposed for the Tagaki hydrolysis system , which , however , had no experimental support at all . Nonligand substrates such as 4 - nitrophenyl acetate ( NA ) were not cleaved by 7 . Recently , Bunton et al . synthesized the C16H33 ...
... proposed for the Tagaki hydrolysis system , which , however , had no experimental support at all . Nonligand substrates such as 4 - nitrophenyl acetate ( NA ) were not cleaved by 7 . Recently , Bunton et al . synthesized the C16H33 ...
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
熱門章節
第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
第 534 頁 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
第 316 頁 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
第 202 頁 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
第 204 頁 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
第 30 頁 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
第 30 頁 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
第 528 頁 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).