Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 1 到 5 筆結果,共 55 筆
第 4 頁
... donor sites and polarizability : ionic ( hard ) ones are those with an oxygen- donor group ( like carboxylate , alcohol ) ; covalent ones ( soft ) are those with sulfur or phosphorus donor atoms ( thioethers , thiolates , phosphanes ) ...
... donor sites and polarizability : ionic ( hard ) ones are those with an oxygen- donor group ( like carboxylate , alcohol ) ; covalent ones ( soft ) are those with sulfur or phosphorus donor atoms ( thioethers , thiolates , phosphanes ) ...
第 5 頁
... donor groups and the oxidation state of the metal ion : e.g. , copper ( II ) is generally found in a square planar , or a tetragonal 5- or 6 - coordinate geometry , whereas copper ( I ) is often found in a tetrahedral geometry . This ...
... donor groups and the oxidation state of the metal ion : e.g. , copper ( II ) is generally found in a square planar , or a tetragonal 5- or 6 - coordinate geometry , whereas copper ( I ) is often found in a tetrahedral geometry . This ...
第 6 頁
... donor groups present in such ligands are thiols , imidazoles , and carboxylates . They are commonly used with the aim of better understanding the natural system and / or making use of certain biological princi- Table 2 Bioligands and ...
... donor groups present in such ligands are thiols , imidazoles , and carboxylates . They are commonly used with the aim of better understanding the natural system and / or making use of certain biological princi- Table 2 Bioligands and ...
第 7 頁
... donor groups are usually bound together in a chelating form ; i.e. , two or more ligand donor groups are linked in such a way that all of them can simultaneously bind to the metal , resulting in a very stable species . Substrates and ...
... donor groups are usually bound together in a chelating form ; i.e. , two or more ligand donor groups are linked in such a way that all of them can simultaneously bind to the metal , resulting in a very stable species . Substrates and ...
第 9 頁
... donor molecule to an ac- ceptor molecule ) 3. Hydrolases ( hydrolytic cleaving of C - O or C - N bonds ) 4. Lyases ( cleaving C - N , C - O , or C - C bonds by elimination ) 5. Isomerases ( causing geometric or structural change within ...
... donor molecule to an ac- ceptor molecule ) 3. Hydrolases ( hydrolytic cleaving of C - O or C - N bonds ) 4. Lyases ( cleaving C - N , C - O , or C - C bonds by elimination ) 5. Isomerases ( causing geometric or structural change within ...
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
熱門章節
第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...