Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 1 到 5 筆結果,共 82 筆
第 4 頁
... coordination sites and hampering normal reac- tions . Toxic metals may substitute nontoxic metal ions in ... COORDINATION CHEMISTRY IN BIOLOGY II.A. General Coordination Aspects The coordination behavior of metals can be categorized into ...
... coordination sites and hampering normal reac- tions . Toxic metals may substitute nontoxic metal ions in ... COORDINATION CHEMISTRY IN BIOLOGY II.A. General Coordination Aspects The coordination behavior of metals can be categorized into ...
第 5 頁
... coordinating ligands are arranged around the metal ion is of meaningful importance for the catalytic activity of the metal ion . In low- molecular - weight coordination compounds usually there are few or no constraints dictating the ...
... coordinating ligands are arranged around the metal ion is of meaningful importance for the catalytic activity of the metal ion . In low- molecular - weight coordination compounds usually there are few or no constraints dictating the ...
第 13 頁
... coordination catalysis by metal ions . Thus , at the molecu- lar level we are dealing with homogeneous catalysis in aqueous media . However , as Dewar has pointed out [ 1 ] , since a proper substrate of an enzyme fits tightly into its ...
... coordination catalysis by metal ions . Thus , at the molecu- lar level we are dealing with homogeneous catalysis in aqueous media . However , as Dewar has pointed out [ 1 ] , since a proper substrate of an enzyme fits tightly into its ...
第 15 頁
... coordination number , spin state , and redox potential of the metal ion and the precise coordination geometry of the complex . Moreover the superstructure of a protein ligand can impose an unusual ( high - energy ) geometry at a metal ...
... coordination number , spin state , and redox potential of the metal ion and the precise coordination geometry of the complex . Moreover the superstructure of a protein ligand can impose an unusual ( high - energy ) geometry at a metal ...
第 16 頁
Jan Reedijk, Elisabeth Bouwman. types : coordination catalysis and organometallic catalysis . Their major character- istics are outlined below . Coordination Catalysis Hard metal center Strong σ donors as ligands ( e.g. , RNH2 , RCO2 ̄ ) ...
Jan Reedijk, Elisabeth Bouwman. types : coordination catalysis and organometallic catalysis . Their major character- istics are outlined below . Coordination Catalysis Hard metal center Strong σ donors as ligands ( e.g. , RNH2 , RCO2 ̄ ) ...
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
熱門章節
第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
第 534 頁 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
第 316 頁 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
第 202 頁 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
第 204 頁 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
第 30 頁 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
第 30 頁 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
第 528 頁 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).