Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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第 1 到 5 筆結果,共 75 筆
第 10 頁
... Figure 2 Structures of some important metal - containing drugs ( R = organic fragment ) . nance ( NMR ) structures and even a few x - ray structures of the so - called zinc fingers and their adducts with pieces of DNA became available ...
... Figure 2 Structures of some important metal - containing drugs ( R = organic fragment ) . nance ( NMR ) structures and even a few x - ray structures of the so - called zinc fingers and their adducts with pieces of DNA became available ...
第 15 頁
... Figure 1 ) . The nature of these ligands plays a crucial role in determining the specificity and activity of metalloenzymes . The ligand may control the coordination number , spin state , and redox potential of the metal ion and the ...
... Figure 1 ) . The nature of these ligands plays a crucial role in determining the specificity and activity of metalloenzymes . The ligand may control the coordination number , spin state , and redox potential of the metal ion and the ...
第 16 頁
... ( Figure 2 ) . In this case substrate activation results in cleavage of the C - Cl bond . In most cases , however , substrate activation by Lewis acids involves electron redistribution without bond breaking ( Figure 3 ) . Thus , many ...
... ( Figure 2 ) . In this case substrate activation results in cleavage of the C - Cl bond . In most cases , however , substrate activation by Lewis acids involves electron redistribution without bond breaking ( Figure 3 ) . Thus , many ...
第 21 頁
... ( Figure 5 ) . Although the 16/18 electron rule is a very useful tool for constructing mechanistic pathways , it should be noted that it completely ignores homolytic mechanisms . It is also noteworthy that it has seldom been applied to ...
... ( Figure 5 ) . Although the 16/18 electron rule is a very useful tool for constructing mechanistic pathways , it should be noted that it completely ignores homolytic mechanisms . It is also noteworthy that it has seldom been applied to ...
第 39 頁
... Figure 2a and b , respectively . However , no evidence was given for either mecha- nism . The role of the metal ions ... Figure 2 Proposed mechanism for acetyl phosphate hydrolysis by Gutsche's metallomi- celle 4 : ( a ) acetyl transfer ...
... Figure 2a and b , respectively . However , no evidence was given for either mecha- nism . The role of the metal ions ... Figure 2 Proposed mechanism for acetyl phosphate hydrolysis by Gutsche's metallomi- celle 4 : ( a ) acetyl transfer ...
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常見字詞
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
熱門章節
第 14 頁 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
第 534 頁 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
第 316 頁 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
第 202 頁 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
第 204 頁 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
第 30 頁 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
第 30 頁 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
第 528 頁 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).