Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 1999年2月2日 - 624 頁 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
內容
1 Introduction to Bioinorganic Chemistry | 1 |
2 Introduction to Homogeneous Catalysis | 13 |
3 Relationships Between Enzymatic and Heterogeneous Catalysis | 23 |
4 Lewis Acid Properties of Zinc and Its Development to Phosphotriester Detoxifying Agents | 33 |
5 Vanadium Haloperoxidases | 55 |
6 Molybdenum and Tungsten Enzymes | 81 |
7 Catalysis by Nitrogenases and Synthetic Analogs | 153 |
8 Biological IronSulfur Clusters with Catalytic Activity | 209 |
10 Oxygen Activation at Nonheme Iron Centers | 269 |
11 Dioxygen Activation at Heme Centers in Enzymes and Synthetic Analogs | 323 |
12 Biological and Biomimetic Catalysis of Manganese Redox Enzymes and Their Inorganic Models | 355 |
Influence of the trans Nitrogen Ligand on Homolytic and Heterolytic Processes | 423 |
14 Formation Structure and Reactivity of Copper Dioxygen Complexes | 469 |
15 Multielectron Transfer and Catalytic Mechanisms in Oxidative Polymerization | 535 |
16 Metalloenzymes with a Quinone Cofactor | 563 |
17 Future Developments | 587 |
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常見字詞
acid Acta active addition analogs appears atom binding Biochem Biochemistry Biol biological bond bound bridging catalase catalysis catalytic changes Chem chemistry cleavage cluster Co⎯C cofactor complex compounds consistent containing coordination copper coupling crystal cycle cytochrome derived dioxygen discussed distance effect electron electron transfer enzyme example Figure first followed formation function give hydrogen hydrogenases hydron hydroxylation important indicate Inorg intermediate involved ions iron kinetic known latter ligand mechanism metal metal ions molecule molybdenum nature nickel nitrogen observed occurs organic oxidase oxidation oxygen peroxide possible potential presence properties proposed protein radical reaction reactivity recent redox reductase reduction reported residue ring role Scheme shown similar solution species spectroscopic stability step structure studies substrate suggest Table tion Trans tungsten x-ray York